Neymar then pitched in with three goals on the spin, the third of which bringing back memories of his formative years at Santos, where he used to skin entire apathetic defences for fun...
Cavani and Ibrahimovic head a list of iconic figures in PSG's all-time scoring charts, with former Portugal worldwide Pauleta behind the pair with 109 goals.
In short, they're walking it.
Di Maria's fourth-minute strike got the rout up and running as he scored for a third Ligue 1 game in a row, curling a fine effort into the top corner to also set the standard for the level of goals in the match.
Brazilian striker Neymar netted four goals in PSG's win vs. Dijon, but he received boos from the home crowd.
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The former Real Madrid and Manchester United winger added a second when he applied the final touch after Neymar lifted the ball over Dijon goalkeeper Baptiste Reynet following a ball through from Cavani. The Argentine made it 2-0 11 minutes later from point-blank range with Dijon in disarray.
Just to rub salt into the wound, Neymar buried a penalty past Reynet in the 83rd minute.
The Uruguay forward has the same number as Zlatan Ibrahimovic, who played for PSG between 2012-16.
Cavani's strike moved him further into the lead in the goalscoring rankings in the French top flight, taking him to the 20-goal mark - four more than his closest rival for the accolade, Monaco's Radamel Falcao.
Neymar released Mbappe as the teenager scored within five minutes of replacing Di Maria, while the Brazilian rounded out a record home win for PSG from the spot after Cavani tumbled to the ground.